We are investigating the reactivities of """"""""carbons adjacent"""""""" closo-dilithiacarboranes toward lanthanide metal halides in TMEDA, but in the absence of oxygen-containing solvents such as THF, to isolate mononuclear, zwitterionic, bent-sandwich lanthanacarboranes as precursors to coordinatively unsaturated 14-electron, do, metal alkyl derivatives. In addition to mass spectrometry and the elemental analyses of the compounds prepared, the multinuclear NMR & IR spectroscopy and where possible EPR spectroscopy, X-ray crystal structure determinations and magnetic measurements will be the integral part of the characterization.

Agency
National Institute of Health (NIH)
Institute
National Center for Research Resources (NCRR)
Type
Biotechnology Resource Grants (P41)
Project #
5P41RR000954-20
Application #
5221750
Study Section
Project Start
Project End
Budget Start
Budget End
Support Year
20
Fiscal Year
1996
Total Cost
Indirect Cost
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