This subproject is one of many research subprojects utilizing the resources provided by a Center grant funded by NIH/NCRR. Primary support for the subproject and the subproject's principal investigator may have been provided by other sources, including other NIH sources. The Total Cost listed for the subproject likely represents the estimated amount of Center infrastructure utilized by the subproject, not direct funding provided by the NCRR grant to the subproject or subproject staff. All ACERT c.w. spectrometers currently utilize conventional ca 100KHz magnetic field modulation for ESR spectral line detection. However, for high-field detection of moderately broad spectral linewidths the utility of this detection technique is severely constrained. Detection of moderately broad HF spectra corresponding to, e.g., spin-labeled proteins in the intermediate slow-motion regime, becomes relatively inefficient when ?Bmod <
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