The sterochemistry of the leucine-2,3-aminomutase reaction and the lysine-2,3-aminomutase reaction is being investigated with the use of stereospecifically labeled leucines and lysines, and with the application of deuterium NMR spectroscopy.
Aberhart, D J (1988) Separation by high-performance liquid chromatography of alpha- and beta-amino acids: application to assays of lysine 2,3-aminomutase and leucine 2,3-aminomutase. Anal Biochem 169:350-5 |
Aberhart, D J; Cotting, J A; Lin, H J (1985) Separation by high-performance liquid chromatography of (3R)- and (3S)-beta-leucine as diastereomeric derivatives. Anal Biochem 151:88-91 |