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Zhou, Ang; Crossland, Patrick M; Draksharapu, Apparao et al. (2018) Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases. J Biol Inorg Chem 23:155-165
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Jasniewski, Andrew J; Que Jr, Lawrence (2018) Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes. Chem Rev 118:2554-2592
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Magherusan, Adriana M; Zhou, Ang; Farquhar, Erik R et al. (2018) Mimicking Class?I?b Mn2 -Ribonucleotide Reductase: A MnII2 Complex and Its Reaction with Superoxide. Angew Chem Int Ed Engl 57:918-922
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Kal, Subhasree; Draksharapu, Apparao; Que Jr, Lawrence (2018) Sc3+ (or HClO4) Activation of a Nonheme FeIII-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene. J Am Chem Soc 140:5798-5804
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Fan, Ruixi; Serrano-Plana, Joan; Oloo, Williamson N et al. (2018) Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-Oxo Intermediate. J Am Chem Soc 140:3916-3928
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Komor, Anna J; Jasniewski, Andrew J; Que, Lawrence et al. (2018) Diiron monooxygenases in natural product biosynthesis. Nat Prod Rep 35:646-659
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Jasniewski, Andrew J; Komor, Anna J; Lipscomb, John D et al. (2017) Unprecedented (?-1,1-Peroxo)diferric Structure for the Ambiphilic Orange Peroxo Intermediate of the Nonheme N-Oxygenase CmlI. J Am Chem Soc 139:10472-10485
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Komor, Anna J; Rivard, Brent S; Fan, Ruixi et al. (2017) CmlI N-Oxygenase Catalyzes the Final Three Steps in Chloramphenicol Biosynthesis without Dissociation of Intermediates. Biochemistry 56:4940-4950
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Khenkin, Alexander M; Vedichi, Madhu; Shimon, Linda J W et al. (2017) Hydrogen-Atom Transfer Oxidation with H2O2 Catalyzed by [FeII(1,2-bis(2,2'-bipyridyl-6-yl)ethane(H2O)2]2+: Likely Involvement of a (?-Hydroxo)(?-1,2-peroxo)diiron(III) Intermediate. Isr J Chem 57:990-998
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Zhou, Ang; Prakash, Jai; Rohde, Gregory T et al. (2017) The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe-O-M Complexes Derived from [FeIV(Oanti/syn)(TMC)]2+ Isomers. Inorg Chem 56:518-527
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