Agency
National Institute of Health (NIH)
Institute
National Institute of General Medical Sciences (NIGMS)
Type
Research Project (R01)
Project #
2R01GM047365-05
Application #
2184766
Study Section
Metallobiochemistry Study Section (BMT)
Project Start
1992-08-01
Project End
2000-07-31
Budget Start
1996-08-01
Budget End
1997-07-31
Support Year
5
Fiscal Year
1996
Total Cost
Indirect Cost
Name
University of Minnesota Twin Cities
Department
Chemistry
Type
Other Domestic Higher Education
DUNS #
168559177
City
Minneapolis
State
MN
Country
United States
Zip Code
55455
Eisenhart, Reed J; Rudd, P Alex; Planas, Nora et al. (2015) Pushing the Limits of Delta Bonding in Metal-Chromium Complexes with Redox Changes and Metal Swapping. Inorg Chem 54:7579-92
Gagnon, Nicole; Tolman, William B (2015) [CuO](+) and [CuOH](2+) complexes: intermediates in oxidation catalysis? Acc Chem Res 48:2126-31
Neisen, Benjamin D; Solntsev, Pavlo; Halvagar, Mohammad R et al. (2015) Secondary Sphere Hydrogen Bonding in Monocopper Complexes of Potentially Dinucleating Bis(carboxamide) Ligands. Eur J Inorg Chem 2015:5856-5863
Dhar, Debanjan; Tolman, William B (2015) Hydrogen atom abstraction from hydrocarbons by a copper(III)-hydroxide complex. J Am Chem Soc 137:1322-9
Yee, Gereon M; Tolman, William B (2015) Transition metal complexes and the activation of dioxygen. Met Ions Life Sci 15:131-204
Halvagar, Mohammad Reza; Solntsev, Pavlo V; Lim, Hyeongtaek et al. (2014) Hydroxo-bridged dicopper(II,III) and -(III,III) complexes: models for putative intermediates in oxidation catalysis. J Am Chem Soc 136:7269-72
Halvagar, Mohammad Reza; Neisen, Benjamin; Tolman, William B (2013) Copper-, palladium-, and platinum-containing complexes of an asymmetric dinucleating ligand. Inorg Chem 52:793-9
Yang, Lei; Tolman, William B (2012) Type 1 copper site synthetic model complexes with increased redox potentials. J Biol Inorg Chem 17:285-91
Gupta, Aalo K; Tolman, William B (2012) Cu(I)/O2 chemistry using a ýý-diketiminate supporting ligand derived from N,N-dimethylhydrazine: a [Cu3O2]3+ complex with novel reactivity. Inorg Chem 51:1881-8
Taguchi, Taketo; Gupta, Rupal; Lassalle-Kaiser, Benedikt et al. (2012) Preparation and properties of a monomeric high-spin Mn(V)-oxo complex. J Am Chem Soc 134:1996-9

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