Professor Kelly is being supported by the Experimental Physical Chemistry Program in spectroscopic studies of small to intermediate size organic radicals. The spectroscopic data will be used to characterize the structure and dynamics of various radicals important as intermediates in combustion processes. The radicals are formed in an atmospheric pressure flow by photodissociation of precursor molecules and are characterized using time-resolved resonance Raman spectroscopy using far ultraviolet radiation. Initial work will concentrate on the spectroscopic characterization of vibrational structure and excited state dynamics in simple radicals, such as the methyl, allyl, cyclopropyl, methylene, cyanomethyl, ethyl, and tertiary butyl radicals.

Agency
National Science Foundation (NSF)
Institute
Division of Chemistry (CHE)
Application #
8923059
Program Officer
Alfons Weber
Project Start
Project End
Budget Start
1990-07-15
Budget End
1993-12-31
Support Year
Fiscal Year
1989
Total Cost
$185,505
Indirect Cost
Name
University of California Davis
Department
Type
DUNS #
City
Davis
State
CA
Country
United States
Zip Code
95618