They propose a comprehensive study of the oxygen-17 nuclear magnetic resonance spectroscopic behavior of a range of oxide superconductors in their normal, and in many cases, superconducting, state. Newer systems will naturally be included, as they become available, as will a series of model perovskites and copper oxides. They will obtain knight shift, linewidth, and spin-lattice (Korringa and Arrhenius) relaxation time (T1) behavior of each of these systems, and relate there to structure, and to the experimental Tc temperatures observed. Where appropriate, oriented samples will be used, to facilitate spectral assignments. They will investgigate the kinetics of oxygen exchange; the effects of sequential oxygenation on NMR/superconducting behavior; the topic of "frozen" states; melt textured growth and the removal of "weak links".

Agency
National Science Foundation (NSF)
Institute
Division of Materials Research (DMR)
Application #
8814789
Program Officer
David Nelson
Project Start
Project End
Budget Start
1989-03-01
Budget End
1992-08-31
Support Year
Fiscal Year
1988
Total Cost
$290,000
Indirect Cost
Name
University of Illinois Urbana-Champaign
Department
Type
DUNS #
City
Champaign
State
IL
Country
United States
Zip Code
61820