Fundamental understandings of new semiconductor materials are key to the development of future functional electronics for various smart applications. Hybrid organic-inorganic halide perovskites (HOIP) have recently emerged as a new family of semiconductor materials with exceptional promise for various functional electronics such as solar cells and light-emitting devices. However, the fundamental solid-state electrochemistry of HOIPs has been less understood, which retards the progress of perovskite technologies. This project addresses this challenge by combining the unique expertise and capacity from Brown University and National Renewable Energy Laboratory. Through the collaborative activities, a novel research platform for exploring the HOIP electrochemistry will be established, which will lead to decisive answers to many long-standing mysteries in the perovskite field and thus have great impacts on the development of clean-energy technologies. Furthermore, this project will contribute to significant enhancement in the PI's research capacity and overall research infrastructure in Rhode Island. It will also provide opportunities for undergraduate and graduate students at Brown University and other institutes in Rhode Island to explore more science subjects in the future.
The goal of this project is to elucidate the key electrochemistry phenomena in hybrid organic-inorganic halide perovskite (HOIP) materials and their correlation to the performance of perovskite solar cells (PSCs). Attainment of this goal will be of vital importance for understanding many exceptional behaviors (e.g. giant switchable photovoltaic effects, photocurrent hysteresis) that have been observed in HOIPs. It will also have strong implication for extending the applications of HOIPs to new electronics and iontronics. A new research platform for clarifying the intrinsic electrochemical properties of HOIPs will be established by combining classical electrochemistry methods (based on Tubandt cell) and advanced materials-characterization approaches. This will contribute to the determination of exact migrating ion types, ion-migration tolerance mechanisms, and ion reactivity of HOIPs with other related device contact materials. Further, the effect of microstructures on the electrochemistry of HOIPs will be investigated, which will be correlated to the performance of PSCs. Based on all these fundamental understandings, engineered microstructures of HOIPs will be synthesized for controlled electrochemical behavior and enhanced PSC performance. The established methodology based on this research will have far-reaching impacts on understanding the broad family of mixed ion-electronic semiconductors and their device applications.
This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
