This Small Business Innovation Research (SBIR) Phase I project will determine feasibility of using new technology to produce high purity lithium metal. The existing energy-intensive production method operates at 460C, has changed little in over 100 years and requires over 35 kWh/kg of lithium metal. The purity of the product is very dependent on the feed material with high purity lithium produced via a further high-temperature distillation step. A current trend returning to using lithium metal to produce high energy batteries will increase demand for high-purity lithium. If successful, the proposed novel electrolyzer will produce higher quality lithium metal at lower processing temperatures and power consumption. This project will test and select suitable components for the electolyzer and demonstrate their use for high purity lithium production.

The broader/commercial impacts of this research are a production method capable of producing large quantities of high-purity battery-grade lithium metal. The requirement for energy storage for transportation and utility applications has generated a large amount of research into high energy density batteries of which protected or sealed lithium metal batteries are being developed. The move to lithium metal batteries will greatly improve the viability and cost effectiveness of a range of energy based technologies, and will have a direct impact on reducing greenhouse gas emissions. Current lithium metal production methods would not be able to meet these demands which would impede installation of these batteries. Furthermore the current process would not be able to produce the required purity of product without energy intensive distillations.

Project Report

This Small Business Innovation Research Phase I project determined the feasibility of using new technology to produce high purity lithium metal. The existing energy-intensive production method operates at 460oC, has changed lttle in over 100 years and requires over 35 kWh/kg of lithium metal. The purity of the product is very dependent on the feed material with high purity lithium produced via a further high-temperature distillation step. A current trend returning to using lithium metal to produce high energy batteries will increase demand for high-purity lithium. The proposed novel electrolyzer would have produced higher quality lithium metal at lower processing temperatures and power consumption. This project tested and selected various components for the electolyzer. Many of the components were demonstrated to be feasibile, but material and chemical properties of one of the components was not sufficeint to demonstrate its use for high purity lithium production. The broader/commercial impacts of this research would have been a production method capable of producing large quantities of high-purity battery-grade lithium metal. The requirement for energy storage for transportation and utility applications has generated a large amount of research into high energy density batteries of which ppotected or sealed lithium metal batteries are being developed. The move to lithium metal batteries will greatly improve the viability and cost effectiveness of a range of energy based technologies, and will have a direct impact on reducing greenhouse gas emissions. Current lithium metal production methods would not be able to meet these demands which would impede installation of these batteries. Furthermore the current process would not be able to produce the required purity of product without energy intensive distillations.

Agency
National Science Foundation (NSF)
Institute
Division of Industrial Innovation and Partnerships (IIP)
Type
Standard Grant (Standard)
Application #
1046620
Program Officer
Gregory T. Baxter
Project Start
Project End
Budget Start
2011-01-01
Budget End
2011-07-31
Support Year
Fiscal Year
2010
Total Cost
$150,000
Indirect Cost
Name
The Electrosynthesis Company, Inc.
Department
Type
DUNS #
City
Lancaster
State
NY
Country
United States
Zip Code
14086