The mission of the TRC is to provide for analyses of quality in the interdisciplinary aspects of the Program, and to provide for methods development for new research areas and in interactions for technology transfer to industry. The equipment component assists in providing basic equipment necessary for individual project research, and for equipment needed for interdisciplinary multiproject research. Research in the program has pointed to the potential application of the methods and results to current questions of environmental hazards that are presented by industry-wide problems. A common issue is the question of the environmental stability, persistence and fate of apparently recalcitrant compounds and the impact of these compounds on human health. The primary TRC project examines whether components of metal-complex azo dyes become bioavailable and thus a threat to human health. Five metal-complex dyes in commercial use will be examined for the constituents of the starting press cake dyes, their organic portions, potential degradation products and free ionic metals. Environmental samples will be press cake from the manufactures, wastewater treatment products, sludges and effluents from textile dye users, and water and sediment samples upstream and downstream from effluent discharges. Analyses will involve HPLC and inductively coupled plasma/mass spectrometry for metal speciation, chemical stability under abiotic and biotic conditions, environmental partition properties and the biological stability of the dyes. Long range goals include biofilm reactor studies of these samples and of environmental samples from other metal producing and using industries.

Project Start
1999-04-01
Project End
2001-03-31
Budget Start
1998-10-01
Budget End
1999-09-30
Support Year
11
Fiscal Year
1999
Total Cost
Indirect Cost
Name
University of Cincinnati
Department
Type
DUNS #
City
Cincinnati
State
OH
Country
United States
Zip Code
45221
McNear Jr, David H; Afton, Scott E; Caruso, Joseph A (2012) Exploring the structural basis for selenium/mercury antagonism in Allium fistulosum. Metallomics 4:267-76
Welsh, Gwendolyn L; Mueller, Kevin E; Soman, Rajiv S et al. (2009) Accessibility of polybrominated diphenyl ether congeners in aging soil. J Environ Monit 11:1658-63
Seo, Youngwoo; Lee, Woo-Hyung; Sorial, George et al. (2009) The application of a mulch biofilm barrier for surfactant enhanced polycyclic aromatic hydrocarbon bioremediation. Environ Pollut 157:95-101
Afton, Scott E; Catron, Brittany; Caruso, Joseph A (2009) Elucidating the selenium and arsenic metabolic pathways following exposure to the non-hyperaccumulating Chlorophytum comosum, spider plant. J Exp Bot 60:1289-97
Chen, Liang; Ovesen, Jerald L; Puga, Alvaro et al. (2009) Distinct contributions of JNK and p38 to chromium cytotoxicity and inhibition of murine embryonic stem cell differentiation. Environ Health Perspect 117:1124-30
Ellis, Jenny; Grimm, Rudolf; Clark, Joseph F et al. (2008) Studying protein phosphorylation in low MW CSF fractions with capLC-ICPMS and nanoLC-CHIP-ITMS for identification of phosphoproteins. J Proteome Res 7:4736-42
Afton, Scott; Kubachka, Kevin; Catron, Brittany et al. (2008) Simultaneous characterization of selenium and arsenic analytes via ion-pairing reversed phase chromatography with inductively coupled plasma and electrospray ionization ion trap mass spectrometry for detection applications to river water, plant extract an J Chromatogr A 1208:156-63
Kubachka, Kevin M; Richardson, Douglas D; Heitkemper, Douglas T et al. (2008) Detection of chemical warfare agent degradation products in foods using liquid chromatography coupled to inductively coupled plasma mass spectrometry and electrospray ionization mass spectrometry. J Chromatogr A 1202:124-31
Seo, Youngwoo; Bishop, Paul L (2008) The monitoring of biofilm formation in a mulch biowall barrier and its effect on performance. Chemosphere 70:480-8
Richardson, Douglas D; Caruso, Joseph A (2007) Derivatization of organophosphorus nerve agent degradation products for gas chromatography with ICPMS and TOF-MS detection. Anal Bioanal Chem 388:809-23

Showing the most recent 10 out of 140 publications