(Project 2: Brusseau, Field, Maier, Chorover) Surface-water and groundwater contamination from acid rock drainage is one of the primary environmental concerns for many hardrock mining sites in the USA. Concomitantly, cost-effective treatment of mining-impacted waters to levels protective of human health and the environment is a critical issue for mitigating the risk associated with hardrock mining sites. The overall goals of this project are to investigate the key physical and biogeochemical processes that control migration and attenuation of mine-drainage contaminants in groundwater, and to develop and test innovative methods for remediation of contaminated groundwater at hardrock mining sites. The project incorporates innovative methods to examine the biogeochemical processes that control contaminant behavior, with a focus on the unique properties and conditions inherent to mining sites in the Southwestern US. The project targets the primary groundwater contaminants of concern at these sites, including arsenic, uranium, and sulfate. This project will advance the state of the science regarding the transport and attenuation of metal(loids) in the subsurface. This will improve the development and parameterization of advanced biogeochemical models, and enhance the accuracy of risk assessments. The project outcomes will also improve the design and implementation of groundwater remediation efforts. Specifically, in-situ biosequestration is one of the very few options that exist for remediation of the large, deep groundwater contaminant plumes that form at hardrock mining sites in the Southwestern US. This method has great potential, but several critical questions exist as barriers to widespread acceptance and adoption. This project will answer these questions. It is anticipated that the application of project outcomes will produce significant cost savings for the clean-up of the nation's inventory of mine waste sites.

Public Health Relevance

(Project 2: Brusseau, Field, Maier, Chorover) Acid rock drainage at metal mining sites creates surface-water and groundwater contamination that presents major potential risks to human health and the environment. This project will investigate the transport and fate behavior of mine-drainage contaminants in groundwater, and it will develop and test innovative methods for remediation of contaminated groundwater. These efforts will help to reduce the risk of these sites, and will reduce the costs for their cleanup.

Agency
National Institute of Health (NIH)
Institute
National Institute of Environmental Health Sciences (NIEHS)
Type
Hazardous Substances Basic Research Grants Program (NIEHS) (P42)
Project #
5P42ES004940-29
Application #
9537573
Study Section
Special Emphasis Panel (ZES1)
Project Start
Project End
Budget Start
2018-04-01
Budget End
2019-03-31
Support Year
29
Fiscal Year
2018
Total Cost
Indirect Cost
Name
University of Arizona
Department
Type
DUNS #
806345617
City
Tucson
State
AZ
Country
United States
Zip Code
85721
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Brusseau, Mark L (2018) Assessing the potential contributions of additional retention processes to PFAS retardation in the subsurface. Sci Total Environ 613-614:176-185
Delikhoon, Mahdieh; Fazlzadeh, Mehdi; Sorooshian, Armin et al. (2018) Characteristics and health effects of formaldehyde and acetaldehyde in an urban area in Iran. Environ Pollut 242:938-951
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Yan, Ni; Zhong, Hua; Brusseau, Mark L (2018) The natural activation ability of subsurface media to promote in-situ chemical oxidation of 1,4-dioxane. Water Res 149:386-393
Madeira, Camila L; Field, Jim A; Simonich, Michael T et al. (2018) Ecotoxicity of the insensitive munitions compound 3-nitro-1,2,4-triazol-5-one (NTO) and its reduced metabolite 3-amino-1,2,4-triazol-5-one (ATO). J Hazard Mater 343:340-346
Liu, Pengfei; Rojo de la Vega, Montserrat; Sammani, Saad et al. (2018) RPA1 binding to NRF2 switches ARE-dependent transcriptional activation to ARE-NRE-dependent repression. Proc Natl Acad Sci U S A 115:E10352-E10361
Thomas, Andrew N; Root, Robert A; Lantz, R Clark et al. (2018) Oxidative weathering decreases bioaccessibility of toxic metal(loid)s in PM10 emissions from sulfide mine tailings. Geohealth 2:118-138

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