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Rees, Julian A; Bjornsson, Ragnar; Kowalska, Joanna K et al. (2017) Comparative electronic structures of nitrogenase FeMoco and FeVco. Dalton Trans 46:2445-2455
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Kowalska, Joanna K; Nayyar, Brahamjot; Rees, Julian A et al. (2017) Iron L2,3-Edge X-ray Absorption and X-ray Magnetic Circular Dichroism Studies of Molecular Iron Complexes with Relevance to the FeMoco and FeVco Active Sites of Nitrogenase. Inorg Chem 56:8147-8158
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Villar-Acevedo, Gloria; Lugo-Mas, Priscilla; Blakely, Maike N et al. (2017) Metal-Assisted Oxo Atom Addition to an Fe(III) Thiolate. J Am Chem Soc 139:119-129
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Rees, Julian A; Martin-Diaconescu, Vlad; Kovacs, Julie A et al. (2015) X-ray Absorption and Emission Study of Dioxygen Activation by a Small-Molecule Manganese Complex. Inorg Chem 54:6410-22
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Brines, Lisa M; Coggins, Michael K; Poon, Penny Chaau Yan et al. (2015) Water-soluble Fe(II)-H2O complex with a weak O-H bond transfers a hydrogen atom via an observable monomeric Fe(III)-OH. J Am Chem Soc 137:2253-64
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Kovacs, Julie A (2015) Tuning the Relative Stability and Reactivity of Manganese Dioxygen and Peroxo Intermediates via Systematic Ligand Modification. Acc Chem Res 48:2744-53
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Coggins, Michael K; Martin-Diaconescu, Vlad; DeBeer, Serena et al. (2013) Correlation between structural, spectroscopic, and reactivity properties within a series of structurally analogous metastable manganese(III)-alkylperoxo complexes. J Am Chem Soc 135:4260-72
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Coggins, Michael K; Sun, Xianru; Kwak, Yeonju et al. (2013) Characterization of metastable intermediates formed in the reaction between a Mn(II) complex and dioxygen, including a crystallographic structure of a binuclear Mn(III)-peroxo species. J Am Chem Soc 135:5631-40
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Coggins, Michael K; Toledo, Santiago; Kovacs, Julie A (2013) Isolation and characterization of a dihydroxo-bridged iron(III,III)(?-OH)2 diamond core derived from dioxygen. Inorg Chem 52:13325-31
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Coggins, Michael K; Brines, Lisa M; Kovacs, Julie A (2013) Synthesis and structural characterization of a series of Mn(III)OR complexes, including a water-soluble Mn(III)OH that promotes aerobic hydrogen-atom transfer. Inorg Chem 52:12383-93
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