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Bhadra, Mayukh; Lee, Jung Yoon C; Cowley, Ryan E et al. (2018) Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes. J Am Chem Soc 140:9042-9045
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Johnston, Esther M; Carreira, Cíntia; Dell'Acqua, Simone et al. (2017) Spectroscopic Definition of the CuZ° Intermediate in Turnover of Nitrous Oxide Reductase and Molecular Insight into the Catalytic Mechanism. J Am Chem Soc 139:4462-4476
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Garcia-Bosch, Isaac; Cowley, Ryan E; Díaz, Daniel E et al. (2017) Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2CuII2(O22-) Species to Form L2CuIII2(O)2 Cores with Enhanced Oxidative Reactivity. J Am Chem Soc 139:3186-3195
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Adam, Suzanne M; Garcia-Bosch, Isaac; Schaefer, Andrew W et al. (2017) Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-O(peroxo) Breakage versus Reductive O-O Cleavage Chemistry. J Am Chem Soc 139:472-481
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Schaefer, Andrew W; Kieber-Emmons, Matthew T; Adam, Suzanne M et al. (2017) Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases. J Am Chem Soc 139:7958-7973
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Solomon, Edward I; Hadt, Ryan G; Snyder, Benjamin E R (2016) Activating Metal Sites for Biological Electron Transfer. Isr J Chem 56:649-659
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Tian, Shiliang; Liu, Jing; Cowley, Ryan E et al. (2016) Reversible S-nitrosylation in an engineered azurin. Nat Chem 8:670-7
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Garcia-Bosch, Isaac; Cowley, Ryan E; Díaz, Daniel E et al. (2016) Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity. Chemistry 22:5133-7
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Cowley, Ryan E; Cirera, Jordi; Qayyum, Munzarin F et al. (2016) Structure of the Reduced Copper Active Site in Preprocessed Galactose Oxidase: Ligand Tuning for One-Electron O2 Activation in Cofactor Biogenesis. J Am Chem Soc 138:13219-13229
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Cao, Rui; Saracini, Claudio; Ginsbach, Jake W et al. (2016) Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy. J Am Chem Soc 138:7055-66
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