9508128 Delaney This research will measure precisely the ferric/ferrous ratios in micrometer-sized areas of a suite of glasses using synchrotron microXANES spectroscopy. Samples characterized by Mossbauer spectroscopy and wet chemical analysis will be used to calibrate the relationship between synchrotron microXANES measurements and ferric/ferrous ratios in the glasses. This technique provides, for the first time, the possibility of measuring cation partition coefficients for ferrous or ferric iron (instead of just elemental iron) because measurements of oxidation state can be made in coexisting phases on a petrologically realistic scale. To calibrate the influence of oxygen fugacity on the ferric/ferrous ratio of glasses, several glasses will be equilibrated at a range of superliquidus temperatures in a controlled fugacity atmosphere and quenched to form glasses.

Agency
National Science Foundation (NSF)
Institute
Division of Earth Sciences (EAR)
Type
Standard Grant (Standard)
Application #
9508128
Program Officer
Maryellen Cameron
Project Start
Project End
Budget Start
1995-08-15
Budget End
1997-06-30
Support Year
Fiscal Year
1995
Total Cost
$50,369
Indirect Cost
Name
Rutgers University
Department
Type
DUNS #
City
New Brunswick
State
NJ
Country
United States
Zip Code
08901