(Project 6; Brusseau, Field) Acid rock drainage and its potential impact on surface-water and groundwater contamination is generally considered to be a primary environmental concern for many hardrock mining sites in the USA. Concomitantly, cost-effective treatment of mining-impacted waters to levels protective of human health and the environment is a critical issue for mitigating the risk associated with hardrock mining sites. The overall goals of this project are to investigate the key physical and biogeochemical processes that control migration and attenuation of mine- drainage contaminants in groundwater, and to develop and test innovative methods for characterization and remediation of contaminated groundwater at hardrock mining sites.
The specific aims of the project are: (1) Investigate the key processes that control migration and attenuation of mine-drainage contaminants at the source-groundwater interface; (2) Investigate the feasibility and long-term efficacy of in-situ biosequestration for the remediation of groundwater contaminated by acid-rock drainage; (3) Develop and apply integrated site characterization methods to evaluate groundwater contamination potential, assess risk, and determine the feasibility of remediation at mining sites. The project incorporates innovative hydrological and biogeochemical methods to develop approaches designed specifically for the unique properties and conditions inherent to mining sites in the Southwestern USA. The project targets the primary groundwater contaminants of concern at these sites, including sulfate, arsenic, selenium, perchlorate, and uranium. This project encompasses experiments conducted across several scales, from the pore-scale to the intermediate-scale to pilot-scale field tests. This project will advance the state of the science regarding the transport and attenuation of metalloids in the subsurface, and their remediation. For example, in-situ biosequestration is one of the very few options that exist for remediation of the large, deep groundwater contaminant plumes that form at hardrock mining sites. This method has great potential, but several critical questions exist as barriers to widespread acceptance and adoption. This project will answer these questions, with a specific focus on novel methods for implementing in- situ biosequestration under the conditions representative of sites in the Southwestern USA. It is anticipated that the application of project outcomes will produce significant cost savings for the clean-up of the nation's inventory of mine waste sites.

Public Health Relevance

(Project 6; Brusseau, Field) Acid rock drainage at hardrock mining sites creates surface-water and groundwater contamination that present major potential risks to human health and the environment. This project will investigate the transport and fate behavior of mine-drainage contaminants in groundwater, and it will develop and test innovative methods for characterization and remediation of contaminated groundwater. These efforts will help to reduce the risk of these sites, and will reduce the costs for their clean-up. We will work with the Research Translation Core to ensure that our research is appreciated and applied by the relevant Superfund stakeholders (e.g., EPA, ATSDR, as well as state, tribal and local regulatory agencies, the mining industry and communities, as appropriate).

Agency
National Institute of Health (NIH)
Institute
National Institute of Environmental Health Sciences (NIEHS)
Type
Hazardous Substances Basic Research Grants Program (NIEHS) (P42)
Project #
2P42ES004940-26
Application #
8918885
Study Section
Special Emphasis Panel (ZES1-LWJ-J (SF))
Project Start
Project End
Budget Start
2015-09-30
Budget End
2016-03-31
Support Year
26
Fiscal Year
2015
Total Cost
$153,645
Indirect Cost
$45,575
Name
University of Arizona
Department
Type
DUNS #
806345617
City
Tucson
State
AZ
Country
United States
Zip Code
85721
Pu, Mengjie; Guan, Zeyu; Ma, Yongwen et al. (2018) Synthesis of iron-based metal-organic framework MIL-53 as an efficient catalyst to activate persulfate for the degradation of Orange G in aqueous solution. Appl Catal A Gen 549:82-92
Brusseau, Mark L; Guo, Zhilin (2018) The integrated contaminant elution and tracer test toolkit, ICET3, for improved characterization of mass transfer, attenuation, and mass removal. J Contam Hydrol 208:17-26
Valentín-Vargas, Alexis; Neilson, Julia W; Root, Robert A et al. (2018) Treatment impacts on temporal microbial community dynamics during phytostabilization of acid-generating mine tailings in semiarid regions. Sci Total Environ 618:357-368
Brusseau, Mark L (2018) Assessing the potential contributions of additional retention processes to PFAS retardation in the subsurface. Sci Total Environ 613-614:176-185
Delikhoon, Mahdieh; Fazlzadeh, Mehdi; Sorooshian, Armin et al. (2018) Characteristics and health effects of formaldehyde and acetaldehyde in an urban area in Iran. Environ Pollut 242:938-951
Hammond, Corin M; Root, Robert A; Maier, Raina M et al. (2018) Mechanisms of Arsenic Sequestration by Prosopis juliflora during the Phytostabilization of Metalliferous Mine Tailings. Environ Sci Technol 52:1156-1164
Yan, Ni; Zhong, Hua; Brusseau, Mark L (2018) The natural activation ability of subsurface media to promote in-situ chemical oxidation of 1,4-dioxane. Water Res 149:386-393
Madeira, Camila L; Field, Jim A; Simonich, Michael T et al. (2018) Ecotoxicity of the insensitive munitions compound 3-nitro-1,2,4-triazol-5-one (NTO) and its reduced metabolite 3-amino-1,2,4-triazol-5-one (ATO). J Hazard Mater 343:340-346
Liu, Pengfei; Rojo de la Vega, Montserrat; Sammani, Saad et al. (2018) RPA1 binding to NRF2 switches ARE-dependent transcriptional activation to ARE-NRE-dependent repression. Proc Natl Acad Sci U S A 115:E10352-E10361
Thomas, Andrew N; Root, Robert A; Lantz, R Clark et al. (2018) Oxidative weathering decreases bioaccessibility of toxic metal(loid)s in PM10 emissions from sulfide mine tailings. Geohealth 2:118-138

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