Syntheses of pentacoordinate sulfure species have been extended to sulfurane imines. The chemistry of these novel species will be explored. Simpler examples of pentavalent carbon species will be sought. The synthesis of an ortho-bridged triarylcarbinol with bridge sulfur atoms will be pursued using new synthetic methodology involving the directed ortho-lithiation of arenesulfonic acids.

Agency
National Institute of Health (NIH)
Institute
National Institute of General Medical Sciences (NIGMS)
Type
Research Project (R01)
Project #
7R01GM036844-01
Application #
3291396
Study Section
Medicinal Chemistry Study Section (MCHA)
Project Start
1985-12-01
Project End
1988-11-30
Budget Start
1985-12-01
Budget End
1986-11-30
Support Year
1
Fiscal Year
1986
Total Cost
Indirect Cost
Name
Vanderbilt University Medical Center
Department
Type
Schools of Arts and Sciences
DUNS #
004413456
City
Nashville
State
TN
Country
United States
Zip Code
37203