Agency
National Institute of Health (NIH)
Institute
National Institute of General Medical Sciences (NIGMS)
Type
Research Project (R01)
Project #
5R01GM067173-02
Application #
6693008
Study Section
Medicinal Chemistry Study Section (MCHA)
Program Officer
Schwab, John M
Project Start
2003-01-01
Project End
2007-12-31
Budget Start
2004-01-01
Budget End
2004-12-31
Support Year
2
Fiscal Year
2004
Total Cost
$235,374
Indirect Cost
Name
University of Wisconsin Madison
Department
Chemistry
Type
Schools of Arts and Sciences
DUNS #
161202122
City
Madison
State
WI
Country
United States
Zip Code
53715
Tereniak, Stephen J; Stahl, Shannon S (2017) Mechanistic Basis for Efficient, Site-Selective, Aerobic Catalytic Turnover in Pd-Catalyzed C-H Imidoylation of Heterocycle-Containing Molecules. J Am Chem Soc 139:14533-14541
Jaworski, Jonathan N; McCann, Scott D; Guzei, Ilia A et al. (2017) Detection of Palladium(I) in Aerobic Oxidation Catalysis. Angew Chem Int Ed Engl 56:3605-3610
Wang, Dian; Stahl, Shannon S (2017) Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)2 and Discovery of Fe(OTf)3 as a Highly Effective Cocatalyst. J Am Chem Soc 139:5704-5707
Clagg, Kyle; Hou, Haiyun; Weinstein, Adam B et al. (2016) Synthesis of Indole-2-carboxylate Derivatives via Palladium-Catalyzed Aerobic Amination of Aryl C-H Bonds. Org Lett 18:3586-9
White, Paul B; Jaworski, Jonathan N; Zhu, Geyunjian Harry et al. (2016) Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions. ACS Catal 6:3340-3348
White, Paul B; Jaworski, Jonathan N; Fry, Charles G et al. (2016) Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions. J Am Chem Soc 138:4869-80
Zultanski, Susan L; Stahl, Shannon S (2015) Palladium-Catalyzed Aerobic Acetoxylation of Benzene using NOx-Based Redox Mediators. J Organomet Chem 52:97-102
Osterberg, Paul M; Niemeier, Jeffry K; Welch, Christopher J et al. (2015) Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical Industry. Org Process Res Dev 19:1537-1543
Zheng, Changwu; Stahl, Shannon S (2015) Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to ?-alkyl vinylarenes. Chem Commun (Camb) 51:12771-4
Wang, Dian; Izawa, Yusuke; Stahl, Shannon S (2014) Pd-catalyzed aerobic oxidative coupling of arenes: evidence for transmetalation between two Pd(II)-aryl intermediates. J Am Chem Soc 136:9914-7

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